S 2 2− in high sulfur bauxite undergoes gradual transformation into S 2 O 3 2−, SO 3 2−, and SO 4 2− during the Bayer process, which leads to adverse effects in production . For example, it causes corrosion of steel equipment [ 3, 4 ], an increase in alkali consumption [ 5 ], a reduction in heat transfer efficiency [ 6 ], and affects ...
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The Bayer process is a chemical process for refining aluminium hydroxide, Al(OH) 3 from bauxite; this aluminium hydroxide is subsequently calcined to produce alumina, Al 2 O 3 . The basis of the ...
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One of the potential sources of rareearth elements (REE) is the industrial waste known as red mud (bauxite residue), in which the majority of REE from the initial bauxite are concentrated via the Bayer process. Therefore, the studies of the subject, both in Russia and outside, focus almost exclusively on red mud processing. This article looks into the possibility of REE concentration into red ...
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Alumina is extracted from bauxite by the Bayer process. The waste slurry generated in this process is called red mud and its solid fraction is called bauxite residue. About 12 metric tonnes of bauxite residue is generated for each tonne of alumina produced ( Kumar et al., 2006 ). The global annual generation of bauxite residue is around 120 ...
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While some oxalate enters the Bayer process with bauxite as oxalic acid adsorbed on various minerals, the majority is created by the oxidation and pyrolysis of bauxite organics under Bayer digestion conditions. The rate of its formation in digestion is principally related to the bauxite organic carbon concentration and composition, and to the ...
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Bayer process is about the production of alumina through the refining of aluminum ore (bauxite). The red mud is insoluble slurry waste that contains different types of oxides. Tremendous amount of this slurry is disposed every year (Marwaha et al., 2018 ).
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Bauxite is the principal ore of aluminium. The impurities present in bauxite are SiO2, iron oxides and titanium oxide (T iO2). Concentration is carried out by heating the powdered ore with a concentrated solution of NaOH at 473 523 K and 35 36 bar pressure. This process is called digestion. Al2O3 is extracted out as sodium aluminate.
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The Bayer process is the principal method for the production of alumina from bauxite worldwide. The modern version of the process (developed in the 1880's) still maintains the key steps of dissolution of aluminarich minerals into hot caustic solution, separation of the insoluble phases, followed by gibbsite precipitation and calcination of the gibbsite to alumina (Al 2 O 3).
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3. concentration on silica concentration in the liquor at various residence time is shown below Caustic Concentration of Liquor Higher the caustic concentration faster will be the dissolution of reactive silica from bauxite in the liquor. But at the same time high concentration of caustic liquor will have a higher equilibrium concentration of the silica lowering the desilication rate. 2. ...
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Red mud is a byproduct of alumina production, and its disposal can have severe environmental consequences. This study experimentally investigates the feasibility of using red mud from the Bayer process for cemented paste backfill (CPB). Different binders and activators were used to improve the mechanical properties, water resistance, and environmental behaviors of red mudbased CPB. In ...
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During the digestion process of the Bayer method, lithium and gallium in bauxite will enter into the sodium aluminate solution (Tang et al. 2020; Xu et al. 2018), which will return to the digestion process for recycling after the precipitation of aluminum hydroxide from the decomposition of crystal to a large amount of red mud discharge, most of the lithium and gallium in the ...
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Bayer's Process of Concentration of Bauxite: This process is applied when bauxite contains more Fe 2 O 3 am less SiO 2. This finely ground calcined ore is digested with 45% NaOH solution in an autoclave under 80 lbs pressure at 150°C for ~ 8 hours. When Al 2 O 3 and SiO 2 go into solution as NaAlO 2 and Na 2 iO 3 respectively. The hot ...
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The Bayer process is a chemical process for refining aluminium hydroxide, Al(OH) 3 from bauxite; this aluminium hydroxide is subsequently calcined to produce alumina, Al 2 O basis of the Bayer process is an understanding of the characteristics of the sodiumhydroxide—sodiumaluminate solution relationship, namely its ability to keep sodiumaluminate in a dissolved state over a wide ...
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Aluminium manufacture is accomplished in two phases: the Bayer process of refining bauxite ore to obtain aluminium oxide (which is carried out at AAL), and the HallHeroult process of smelting the ... The maximum concentration of alumina dissolved in the caustic, known as the ratio (as Al 2 O 3 /Na 2 CO 3), occurs in digestion, while the
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The research on pressure leaching started in 1887. Karl Josef Bayer was the first one who proposed to leaching bauxite with sodium hydroxide solution at a temperature of 413453 K to obtain sodium ...
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Bayer's method: In this method, bauxite powder is taken and concentrated (45%) and sodium hydroxide solution is added and then heated in a closed vessel at 433 K temperature and 5 to 6 bars of pressure, for 6 to 8 hours, so that aluminium oxide present in bauxite is converted into sodium aluminate which is soluble in water. In bauxite, in ...
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The concentration of the Bauxite ore into alumina is done by Bayer's process. Alumina is then refined into pure aluminium metal through the HallHéroult electrolytic process. Aluminium is too high in the electrochemical series (reactivity series) to be extracted from its ore using carbon reduction.
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This dissolves aluminium oxide present in bauxite due to the formation of sodium aluminate, (N a A l O 2 ). A l 2 O 2 . H 2 O + 2 N a O H → 2 N a A l O 2 + 3 H 2 O. Since, N a O H a strong reducing agent, it is used in Bayer's process.
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The Bayer process is used for producing alumina (Al 2 O 3) from bauxite process was developed and patented by Karl Josef Bayer in 1887 [], which led to a dramatic reduction in the cost of aluminium process involves the following operations: mining, dissolution of the alumina at elevated temperatures, the addition of flocculants, precipitation of pure gibbsite, regeneration of ...
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The Bayer process is used for refining bauxite to smelting grade alumina (Al 2 O 3), the precursor to aluminium. ... (Na2Ox or K2Ox) increases with an increase in concentration of the counter ion ...
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The Bayer process, with various modifications, is the most widely used method for the production of alumina, and all aluminum is produced from alumina using the HallHéroult electrolytic process. Refining the ore. aluminum processing: Bayer process. Principal operations in the Bayer process of refining bauxite to alumina. (more) There are a ...
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Alumina Production (Bayer Process) The aluminium production starts with the production of alumina from bauxite according to the socalled Bayer process. In the Bayer process, caustic soda (NaOH) is used to extract alumina from bauxite in digesters. High temperatures and pressures are required for this process (Kuenen et al. 2016).
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Solution. The correct option is D Leaching. Bauxite ore is concentrated by the process of leaching. It is a process in which a suitable solution is added to the ore. A chemical reaction takes place between ore and solution in which the ore dissolves in the solution. The insoluble impurities are filtered off.
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The Bayer process is used for refining bauxite to smelting grade alumina, the precursor to aluminum. Typically, depending upon the quality of the ore, between and tonnes of bauxite is required to produce 1 ton of alumina. The Bayer process involves the digestion of crushed bauxite in the concentrated sodium hydroxide (caustic) solution at
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The slurry from desilication is mixed with NaOH (P13/MX101) up to concentration of 10%, ... The Bayer process is used for refining bauxite to smelting grade alumina (Al 2 O 3), the precursor to ...
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ALUMINA FROM BAUXITE: THE BAYER PROCESS. Bauxite, the principal ore used for aluminum smelting, is named after Les Baux, Provence, the village where the first deposits were discovered. Bauxite contains hydrated alumina equivalent to as much as 4060% Al 2 O 3, and is free of the other siliceous materials leached out over time. However it ...
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In the Bayer process, the digestion temperature is an important factor in determining the alumina digestion rate. In this study, the digestion efficiency of the ore at different temperatures was investigated under the following conditions: caustic concentration 240 g/L, initial molar ratio, lime addition 15%, molar ratio of digested liquid ...
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Bayer's process for concentration of bauxite. Ans. Bayer's process is used to obtain pure aluminium oxide from bauxite ore. The bauxite ore is concentrated by chemical separation. Bauxite contains impurities like iron oxide and silica. The bauxite ore is powdered and heated with sodium hydroxide under high pressure in the furnace.
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Alumina Extraction Problem. In the standard Bayer Process for refining bauxite to produce alumina, the dissolution of the alumina in the ore to form sodium aluminate is accomplished in autoclaves under high pressures varying from 70 to 200 pounds per square inch. However, some lateritic bauxite ores are readily soluble in caustic, making it ...
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Baeyer's process is used to leach Red Bauxite, which has Fe2O3 as the chief impurity. Serpeck's process, on the other hand, is used to leach White Bauxite, which has Silica as main impurity. Both are efficient for their respective ores. But Baeyer's process is more frequently used, as Bauxite, more often than not, is also a source of Gallium ...
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