Abstract In this study, the steam reforming of naphthalene and pyrene as heavy tar model compounds was investigated experimentally in a horizontal tube reactor and theoretically using the CHEMKIN simulation. The experimental results revealed that the reactivity of naphthalene was higher than that of pyrene in the presence of steam. The carbon content converted to soot is a little more than ...
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The naphthalene content in the commercial product derived from coal tar by the proposed method is wt %. The yield of naphthalene is wt %. The energy consumption in the basic three ...
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Odour: Peculiar, naphthalenelike (Singh, Goyal and Kaur, 2015) ... PROCESS DESCRIPTION Coal Tar ... 2019. Coal Tar Production Processes and Potential of PAHs Release into the Environment. [online ...
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The gasification process was started by igniting a coal seam using a pyrotechnic charge. The ignition occurred with low oxygen flow rate (2 Nm 3 /h) supplied into the reactor inlet. After ignition of the coal, the oxygen flow rate was increased to 10 Nm 3 /h. The process initiation was considered complete when the concentration of oxygen in the process gas was below 1%.
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Naphthalene has a distinctive, strong odor, which is often described as sweet or tarlike. Its melting point is around 80°C (176°F), and it boils at around 218°C (424°F). Synthesis and Production. Naphthalene is predominantly produced from coal tar, a byproduct of the coal gasification process.
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Coal Tar and its Distillation Processes. Coal tar, also known as crude tar, is the byproduct generated during the high temperature carbonizing of coking coal for the production of the metallurgical coke in the byproduct coke ovens. It is a black, viscous, sometimes semisolid, fluid of peculiar smell, which is condensed together with aqueous ...
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But nowadays Bitumen has replaced coal tar to serve this purpose. Naphthalene balls used as moth repellent in the storage areas are the derivatives of coal tar. ... The production process is distinct, both physically and chemically, from that used to create a range of gaseous fuels known variously as manufactured gas, syngas, hygas, Dowson gas ...
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Naphthalene was first isolated from coal tar in 1819 by Alexander Garden; it represents about 10% of this complex mixture of aromatics. The industrial importance of naphthalene dates from the latter half of the last century, owing mainly to the ease with which it can be converted into sulfonic acids and thence also to the naphthols, for use as dyestuffs intermediates.
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In a process for obtaining substantially sulfur free pure naphthalene from bituminous coal tar and thionaphthene as a byproduct, a dephenolized thionaphthenecontaining naphthalene fraction from oxidative purification is extracted with concentrated sulfuric acid and acetic acid anhydride in benzene.
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Coal tar is a byproduct of coal that is released from various processes of the coal gas and coking process. It is semiliquid in nature with a density of to g/cm 3 and has a foul smell [].. Polycyclic aromatic hydrocarbons (PAHs) are a group of organic compounds that are lifethreatening because of their chemical structures, that consist of benzene rings bonded in a linear and ...
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Coal tar naphthalene oil fraction (CTNOF) is typically obtained as a byproduct of the coking process in steel production. When coal is subjected to high temperatures in the absence of air (coking), it undergoes thermal decomposition, yielding various byproducts including coal tar [].This tar can be further processed to extract different fractions, one of which is naphthalene oil [2, 3].
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Coal tar is a byproduct of metallurgical coke or oil coke production. There are many works devoted to an increased yield and improved quality of needle coke [15]. Coal tar has a complex composition with a high level of valuable aromatic compounds, like phenol, naphthalene, anthracene, etc. [6].Due to its content, coal tar can be used as a rich
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Coal tar ( ) and coal tar pitch ( ) are the byproducts of the hightemperature treatment of coal to make coke or natural gas. These chemical products usually are thick, black or dark brown liquids or semisolids with a naphthalenelike odor. Coal tar also has a sharp, burning taste.
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It processes the naphthalene fraction from the rectification of coal tar so as to produce naphthalene of grade A and type II according to Technical Specifications TU 14797. Until November 2020, the naphthalene was produced at MMK by solidification of the naphthalene fraction and subsequent mechanical separation of the naphthalene crystals ...
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To trace the behavior of naphthalene in the pyrolysis of coal tar, the pyrolysis of coal tar containing 14Clabeled naphthalene was carried out at 800−950 °C for 40−50 s. It was found that naphthalene has significant pyrolysis reactivity. The distributions of the radioactivities in compounds with 3−5 rings were,, and % at 800, 900, and 950 °C for 50 s, respectively ...
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naphthalene oil. NPCs. normalphase columns. OBSG. octyl bonded silica gel. OCAs. ... while the latter is a byproduct from coal coking process [1]. The output of coal tar accounts for 35% of coals in the furnace [2]. ... Li YC, Xin WL, Huang MG, et al. Industrial production technology of coal series needle coke. CN A, ...
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Naphthalene is the simplest polycyclic aromatic hydrocarbon, and can be used as a precursor to many other complex aromatics. Current industrial processes remove it from coal tar or petroleum during the refining and distillation steps. The process reported here is much greener, albeit on a much smaller scale.
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Naphthalene is the most simple, commonly found, and most watersoluble PAHs in the environment. It is produced from coal tar fraction by crystallization and distillation. It is often used as dispersants in natural and synthetic rubbers, in the production of naphthalene sulfonate superplasticizers for concrete, in paints, tanning agents in the leather industry, in the production of the ...
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PRODUCTION Naphthalene may be produced from either coal tar or petroleum. Distillation and fractionation of coal tar is the most common production process. The middle fraction (containing most of the naphthalene) is cooled, crystallizing the naphthalene. The crude naphthalene may be refined by distillation, washing, and
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Naphthalene (also known as naphthalin, naphthaline, moth ball, tar camphor, white tar, or albocarbon), is a crystalline, aromatic, white, solid hydrocarbon, best known as the primary ingredient of is volatile, forming a flammable vapor. Each molecule of this substance consists of two fused benzene rings. As its most abundant single component, it is obtained from coal tar ...
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Naphthalene was first isolated from coal tar in 1819 by Alexander Garden; it represents about 10% of this complex mixture of aromatics. The industrial importance of naphthalene dates from the latter half of the last century, owing mainly to the ease with which it can be converted into sulfonic acids and thence also to the naphthols, for use as dyestuffs intermediates.
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An online condensation system was designed to separate coal tar during cooling process. ... The typical contents of most common specialties in different fractions for coal tar are Light oil, Phenol oil, Naphthalene oil, washing oil, anthracene oil. ... The production yield of total tar was about %, %, % and % for 500, 600, 700 ...
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The organic chemistry industry is based on organic compounds derived from coal, petroleum and gas. Coal tars derived from the carbonisation process are complex mixtures, of which the polycyclic aromatic hydrocarbons (PAH's) are the main component. One of the most important PAH's is naphthalene, which represents between 10 to 12% of the recent years, new applications for industrial ...
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Naphthalene is produced by the following processes: 1. Recovery from coal tar. 2. From petroleum Unidak process Hydeal process Process given by faith. 1. Recovery from coal tar: The tar acidfree chemical oil is charged to the system where most of the low. boiling components,, benzene, xylene, and toluene, are removed in the lightsolvent ...
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Coal tar is a hazardous and toxic waste, a byproduct of coal gasification processes. Coal tar is a waste produced in industrial fields such as steel, power plant, and the cement industry. As a ...
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A kind of method for preparing naphthalene at first is a Doak Tar Oil, and the boiling range of further purifying is 205～235 ℃ a coal tar distillate that obtains like this is commonly referred to naphtalene contain the such heterocycle component of naphthalene, methylnaphthalene, phenolic compound and benzothiophene, (G, people such as Gilbert, Ind, Eng, Chem, 53 ...
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Most naphthalene is derived from coal tar. From the 1960s until the 1990s, significant amounts of naphthalene were also produced from heavy petroleum fractions during petroleum refining, but today petroleumderived naphthalene represents only a minor component of naphthalene production. Naphthalene is the most abundant single component of coal tar.
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naphthalene oil of coal tar [3538]. Therefore, further explorat ions on the use of catalysts to promote LRC pyrolysis staged utilization to produce naphthalene oilrich
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At the moment, most of the aluminum smelters utilize coal tar pitch as binder in their prebaked carbon anode (and graphitized carbon cathode) production processes. Hence, the prediction of the thermodynamic properties of PAHs present in coal tar pitch aimed at phase behavior description of coal tar pitch during heat treatment will be the main ...
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The naphthalene content in the commercial product derived from coal tar by the proposed method is wt %. The yield of naphthalene is wt %. The energy consumption in the basic threecolumn system is Gcal/t of commercial naphthalene (of purity wt %). If heat is recycled in the threecolumn system, the energy consumption is ...
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But because that its relative density is higher than and asphaltene content is close to 50% [6] (mass fraction), hightemperature coal tar is not suitable for the production of aerospace fuel. Medium and low temperature coal tar is a liquid product with high condensation degree obtained by pyrolysis of lowrank coal at 600 to 800°C.
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The naphthalene samples studied in this work were produced by the chemical industry. Fig. 1 shows a process for the production of naphthalene with different degrees of purity. The refined naphthalene came from the catalytic hydrogenation process, (NAFR) (% purity); the industrial naphthalene from a series of distillations (NAFD) (% purity) and the crystallised naphthalene (NAFC) (99 ...
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Report No. COAL TAR CHEMICALS JAMES J. L. MA December 1976 A private report by the a PROCESS ECONOMICS PROGRAM STANFORD RESEARCH INSTITUTE MENLO PARK, CALIFORNIA
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Chemical Abstracts Service Registry Number: CAS (Coal tar creosote); CAS (Wood creosote). Synonyms: Coal tar oil; Brick oil; Heavy oil; Naphthalene oil; Liquid pitch; Wood creosote. Chemical/Pharmaceutical/Other Class: Phenolic Compound. Chemical Formula: A distillate of coal that contains an estimated 162 different compounds.. Estimated makeup is as follows: aliphatic ...
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يرغب أحد موردي المواد من بلجيكا في إنتاج مسحوق الحجر الجيري لملابسه...
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