Bauxite is widely used to produce alumina. There are many bauxite resources with high iron content. These resources could not be processed and utilized efficiently due to the high concentration of iron (Fe). The alkaline leaching process has been proposed to remove iron from these bauxite resources. Therefore, in this study, the alkaline leaching process was employed, and the effects of sodium ...
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A closedloop valorization process, combining carbothermic smelting and acid baking water leaching was developed to recover scandium, aluminum, and iron from bauxite residue, a major side product of aluminum production. This process employs carbothermic smelting to recover 99% of the iron in the starting residue as crude metallic iron, which can be separated from slag that contains ...
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In the leaching method, bauxite ore is digested with a concentrated solution of N a O H that produces X. When C O 2 gas is passed through the aqueous solution of X, a hydrated compound Y is precipitated. X and Y are N a [A l (O H) 4 ] and A l 2 O 3 ⋅ x H 2 O respectively.
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The process combines carbothermic smelting, acid baking water leaching, and thermal desulfation to efficiently extract the target materials from the bauxite residue without producing hazardous solid residues, while enabling the recovery and recycling of the major process reagents: CaO, SiO 2, and H 2 SO 4. Through systematic testing, the ...
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The leaching process with dilute HNO 3 was performed at pilot scale and optimized for the extraction of scandium from bauxite residue ( OchsenkühnPetropoulou et al., 2002 ). Xue et al. (2010) found that at a reaction temperature of 90 °C and an L/S ratio of 3:1, over 80% of the scandium in bauxite residue could be leached by H 2 SO 4.
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1. Introduction. Red mud (RM) is a waste generated during bauxite processing for alumina production. The most common method for bauxite processing is the Bayer process, where raw material is digested under high pressure by NaOH to obtain a pregnant sodium aluminate solution [].During highpressure leaching, nonsoluble elements such as iron, titanium, and refractory or precipitated during ...
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Bayer process solution, in which a bauxite is subsequently leach ed for alumina extraction, and an alkaline solution with a concentration of 400 g L 1 Na 2 O, to c arry out similar investigations.
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In this study, a novel process of lowtemperature sulfating roastingwater leaching is presented to extract vanadium from the bauxitetype vanadium ore. Addition of sulfuric acid enhanced the ...
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In general, the lithium content in bauxite ore is negatively correlated with the alumina content,, the lithium content in bauxite decreases with increasing Al 2 O 3 content. 25,28 Lithium in bauxite tailings 27 can be recovered using acid leaching; however, this leaching process is not selective and the leachate purification process is ...
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The Bayer process is used worldwide for the alumina production. This process involves the alkaline leaching of bauxite to extract Al, followed by the precipitation of Al(OH) 3 to recycle the solution [1,2,3].The leaching process results in the formation of a solid residue, commonly referred to as a bauxite residue, which consists of iron minerals, hydrous aluminosilicates, which are formed ...
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The bauxite selection that can be insitu leaching mining needs to solve the following problems: (1) whether it is permeable to ensure that the leaching solution can flow in the ore layer; (2) whether it is soluble, which can ensure the leaching rate, the content of beneficial minerals in the leaching solution and the consumption of leaching ...
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Bauxite residue, the high alkaline and finegrained byproduct of Bayer process for alumina's production, is a material rich in numerous minerals and elements of high value and technoeconomical interest in high tech applications such as rare earths, including scandium. Lately, the European Committee has characterized scandium as a critical element because of its risk supply chain.
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The process involves baking of bauxite residue with sulfuric acid (12 mL/g, 120200 °C, 224 h) to generate metal sulfates and further decomposition of sulfates (except RE) at high temperatures (600800 °C) and water leaching to dissolve REEs [14,15,16,17]. The process is not costeffective due to the very low starting concentration ...
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Red mud (RM) is a waste generated during bauxite processing for alumina production. The most common method for bauxite processing is the Bayer process, where raw material is digested under high pressure by NaOH to obtain a pregnant sodium aluminate solution [].During highpressure leaching, nonsoluble elements such as iron, titanium, and refractory or precipitated during washing step aluminum ...
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At the same time, as a secondary resource, its aluminum content can reach 50%, which is close to that of mediumgrade bauxite; thus, it can be used as a substitute for bauxite resources. We propose a new method for extracting aluminum from fly ash via leaching. By designing the thermal reaction system of the molten brine, highpurity hydroxyl ...
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Principle processflow diagram of bauxite leaching with HCl based on reference [112]. Many metallic elements in bauxite can be leached in an acid solution. Thus, iron, aluminum or other metallic elements are leached and recovered together during the acidleaching process. However, some problems with acid treatment remain, including severe ...
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In this study, metal extraction from bauxite ore was carried out with a twostage leaching process. At the first stage, bauxite ore was leached under atmospheric conditions with oxalic acid, iron ...
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Red mud, also referred to as bauxite residue, is the largest process waste produced during alumina production from bauxite ore by the Bayer method. Approximately 12 tons of red mud are produced ...
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The research on pressure leaching started in 1887. Karl Josef Bayer was the first one who proposed to leaching bauxite with sodium hydroxide solution at a temperature of 413453 K to obtain sodium ...
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The calcification‑carbonation method is a novel technology recovering Na 2 O and Al 2 O 3 from bauxite residue through mineral transformation, which realizes the harmless treatment of bauxite residue simultaneously. It is mainly realized by two key transformation steps such as calcification transformation and carbonation transformation of the slag phase, and multiple wet process series steps.
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During the Bayer process, REEs Fe, Ti and other undissolved material along with remain unchanged. As a result rare earths end up in BR with an enrichment factor of approximately 2 comparing to the initialore [3]. Therefore, the aluminum industry throughthe Bayer process concentrates the critical metals found in bauxite into bauxite residue.
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Bauxite mine tailings can be used as the reserve resources of aluminium and lithium. In this study, a less energy consumption treatment method for extracting aluminium and lithium from bauxite mine tailings has been proposed, which used mixed acid to leach aluminium and lithium from tailings directly, avoided roasting for reducing energy consumption, and obtained effective minerals ...
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The process consists of the following steps: calcination of bauxite, leaching of calcined bauxite in hydrochloric acid, filtration of residue, crystallization of A1C1 H 2 O, decomposition of AlCl H 2 O crystals to produce A1 2 O 3, regeneration of hydrochloric acid for recycle into the leaching step.
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Hall's process for leaching of alumina from bauxite: (1) Bauxite ore and sodium carbonate are fused toghether to convert aluminium oxide into soluble sodium metaaluminate. The insoluble residue contains the impurities of silica and iron oxide. The fused mass is treated with water.
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Bauxite residue (BR), an alkaline industrial waste, is a major byproduct of the alumina production process known as the Bayer process. The Bayer process generates a byproduct known as bauxite residue (red mud). This residue was leached with sulfuric acid in a pilot plant of Mytilineos to recover scandium. Scandium was selectively recovered in pilotscale experiments using ion exchange.
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The process of Leaching is used to concentrate the ore. NaAlO 2 + 2H 2 O → NaOH + Al(OH) 3. Serpek's process: This process is used when the bauxite ore contains a higher percentage of silica as an impurity. In this process, powdered bauxite ore is mixed with carbon (coke) and heated to 1473K in a current of nitrogen.
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1. Introduction. Red mud (RM) is a solid waste generated by alkali (NaOH) leaching of bauxite by the Bayer process for alumina production [].More than one ton of RM is produced for one ton of alumina (Al 2 O 3), and over 150 Mt of RM is annually stored in landfills and sea [].The RM utilization degree is extremely low due to the high Na, Al, Si, and Ca content because these elements increase ...
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The separation of iron and aluminum in highiron bauxite has been a field of interest for quite a while. For example, in the early studies of iron removal from bauxite, acid leaching [9,10,11] and biological leaching [12,13] were applied. In the process of acid leaching, hematite can be removed by acid dissolution.
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The acid leaching reactions of the bauxite would be thermodynamically easy and completed. Under the conditions that ore granularity is less than −55 μm, the L/S ratio is 100:7, and the leaching temperature is 373383 K, the leaching time is 120 min and the concentration of HCl is 10%, both the leaching rates of Al and Fe are over 95%.
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The separation of the alumina from the impurities in the bauxite ore is usually accomplished by the Bayer Process. In this process the ground bauxite is leached with caustic soda (NaOH) to produce soluble sodium aluminate (NaAlO2), leaving the impurities in the insoluble residue. The aluminate solution is then decomposed producing Al (OH)3 ...
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