The properties of the carbon materials obtained as the final product of coal tar pitch carbonization process are a consequence of the type of chemical and physical phenomena occurring through the process. A new simplified approach for modeling of the primary carbonization is presented to provide the semiquantitative knowledge about the process useful for improving the efficiency of the ...
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Coal tar pitch is a solid product of coal tar distillation, accounting for about 5060 wt% of HTCT (Liu et al., 2018). CTP is a complex mixture composed of PAHs and their derivatives (Zhou et al., 2011), in addition to small particles that are entrained from coking and concentrated in the pitch during tar distillation (Baron et al., 2016).
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The process of distilling coal tar containing a substantial amount of naphthalene and separating it into fractions, which comprises continuously feeding the coal tar containing moisture into a rst stage maintained at an absolute pressure of 50 to 150 mm. of mercury and at a temperature of between 80 and 140 C. and there flashing water and oil ...
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(BSF) of total particulate matter present during the destructive distillation or carbonization of coal for the production of coke (Ref. ). Coal tar is obtained by the distillation of bituminous coal (Ref. ). Coal tar pitch is composed almost entirely of polynuclear aromatic compounds and constitutes 4865% of the usual grades of coal tar.
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1. Tar properties. Coal tar consist of complex hydrocarbon [1] with a wide molecular weight range which make it as a black, viscous liquid [2].It mainly comes from coal carbonization [3] and fast pyrolysis process (biomass gasification [4], biomass pyrolysis [5], coal gasification [6] and coal pyrolysis [7]).Its amount for mass % of the feed coal is usually from to 25.
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Pyridine is produced either by isolation from natural sources such as coal, or through chemical synthesis (HSDB 1989). Pyridine is produced by the fractional distillation of coaltar residues (HSDB 1989; NSC 1978; Santodonato et al. 1985) in which 1 ton of coal produces ... Facilities that manufacture or process pyridine are shown in Table 4l. ...
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For a more detailed description of the coal tar distillation process, including coaltar pitch, the reader is referred to IARC Monograph Volume 92 (IARC, 2010), and to the Monograph on Occupational Exposures during Coaltar Distillation in this volume. Human exposure Occupational exposure
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Two mediumlow temperature coal tars (MLCTs) derived from the pyrolysis of lowgrade bituminous coal were separated into 11 narrow fractions by true boiling distillation.
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Crude phenols extracted using organic solvent from the wastewater of a typical fixedbed gasification process was used as a raw material, and the distillation range was analyzed. The wide and narrow fractions of the raw material derived from distillation range analysis were cut using a real boiling point distillation device. The phenolic compounds in the different fractions were then ...
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Most of the chemicals derived from coal come from byproducts produced during the coking process. Coal is used to make coke to make steel. Coke gas (also called foul gas) contains coke tars, ammonia, and light oils. Tars are recovered and used to make tar derivatives. Ammonia is recovered as an aqueous solution or as an ammonium sulfate salt.
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The separation of coal tar into fractions by distillation is studied on periodic laboratory apparatus using columns of different type, with different heating rates of the tar, distillation temperatures, and treatment times. The composition of the light, phenolic, naphthalene, absorbing, and anthracene fractions is determined by chromatography. The results may be used in developing technology ...
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1. Introduction Coal gasification technology has become an important technology to produce alternative fuels to replace gas and oil fuels. But on the other hand, coal gasification byproducts, including coal tar, sulfur, ammonium sulfate and crude benzol, become a problem to the environment.
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Abstract. Research on the processing of coal tar and benzene products at AO VUKhIN is reviewed. From its founding, the Eastern Research Institute of Coal Chemistry (AO VUKhIN) has studied not only coal and metallurgicalcoke production but also coking byproducts such as coal tar and raw benzene. The first research in this area, directed by ...
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Phenolic compounds are mainly derived from coal tar and coal liquefaction oil. The traditional acidbase separation method, also called caustic washing can result in serious environmental problems. In this work, we used ethanolamine (C 2 H 7 NO) to separate phenolic compounds from coal tar rather than caustic washing. Although a slightly lower efficacy of separation was obtained with C 2 H 7 ...
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PDF | Coal tar is a liquid byproduct of the process of coal gasification and carbonation. ... Using Distillation, Journal of the Japan Petroleum Institute, 2006, 49(6), 326334. ... a continuous ...
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Coal Tar Distillation Coal tar pitch . is . the residue from the distillation of coal tar and represents from 30% to 60% of the tar. It is a complex, bituminous . sub stance and has been estimated to contain about . 5,000 compounds. Of these, less than 130 have been isolated and identified. The presentday process for fractionating coal tar ...
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temperatures above 330° C. in the distillation residue for a longer period of time, results in considerable ther mal decomposition, the fluorene fraction has to be con sidered the highestboiling coal tar ingredient, which could be recovered by direct distillation from the residue with the use of a high reflux ratio.
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Characterization of MiddleTemperature Gasification Coal Tar. Part 3: Molecular Composition of Acidic Compounds. Coal tar has been considered as a potential energy alternative because of dwindling supplies of petroleum. To determine if the coal tar could be refined and upgraded to produce clean transportation..
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Conventional carbon black production occurs by pyrolysis after heavy aromatic feedstock is injected into the postcombustor region of furnace black reactors. The current work examines the conversion of the coal tar distillate in turbulent spray flames to demonstrate a more compact reactor configuration. Coal tar distillates diluted in toluene is atomized and burned in a standardized flame ...
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Destructive Distillation of ... gas, and must be regarded as a tarconserving process, while exceedingly slow distillation gave much poorer yields of tar, but high coke yields. ...
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1. Exposure Data Manufacturing process Coal tar is obtained by cooling the gas that is formed during the destructive distillation of coal to approximately ambient temperature. It is a black, viscous liquid composed primarily of a complex mixture of condensedring aromatic hydrocarbons.
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The regularities of changes in the main characteristics of coal tar pitch (softening point, ash content, volatile matter yield, content of α, α 1, α 2, γ and βfractions) obtained by coal tar distillation, were studied changing three process parameters tar heating rate, temperature and duration of isothermal mathematical model obtained in the form of regression ...
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The coal tar evaluation process of its constituent components is carried out by distillation, with a high level of naphthalene purity achieved up to 96%. The coal tar distillation...
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2019, Pages 439487 15 Coal tar: a byproduct in cokemaking and an essential raw material in carbochemistry María Antonia Diez, Roberto Garcia Add to Mendeley https://// Get rights and content Abstract
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Its IUPAC name is 'Coal Tar Pitch, High temperature". Its CAS number is and EINECS number is . It is the shiny, darkbrown to black residue produced by distillation of coal tar. Coal tar pitch contains a large number of substances. It is solid at room temperature and consists of a complex mixture of numerous polycyclic ...
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Its CAS number is . It is acidic in nature and is water insoluble. Coal tar represents a mixture of condensable volatile products formed during the destructive distillation of bituminous coal. Composition is variable, but generally consists of 0 % to 2 % of light oils (chiefly benzene, toluene, and xylene), 16 % to 18 % of middle oils ...
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The regularities of changes in the main characteristics of coal tar pitch (softening point, ash content, volatile matter yield, content of α, α 1, α 2, γ and βfractions) obtained by coal tar distillation, were studied changing three process parameters tar heating rate, temperature and duration of isothermal mathematical model obtained in the form of regression ...
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hydrogen, initially bound to the coal, is evolved as such or in the form of volatile compounds. These volatile compounds (tar, crude benzol, water, and coke oven gas) contain, moreover, the major proportion of oxygen initially bound in the coal and also a proportion of its sulphur and nitrogen. Table 3.
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Chapter PDF Download to read the full chapter text References Wombles, Robert H., Baron, John Thomas, "Laboratory Anode Comparison of Chinese Modified Pitch and Vacuum Distilled Pitch", TMS Light Metals 2006. Google Scholar
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presumably because some components of the coal tar pitch and the phenolic resin are more likely to form carbon nanotubes. A suitable modifier for the formation of the carbon nanotube structure is added in an amount of 25%. 4. Conclusion (1) Coal tar pitch modified phenolic resin is a good process condition for the formation of graphene at
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of 2 COAL TAR DISTILLATION (EIRI1092) Coaltar is produced by the dry distillation of coal and is therefore a by product in the manufacture of coal gas. For a considerable time after the discovery of coal gas, the tar produced was considered merely an encumbrance and was used mainly as a pigment or fuel. The purification of coaltar is
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Abstract. IN "Coal Tar Distillation" the author has produced a book which will assuredly find a place in the libraries of technologists engaged in the study of the destructive distillation of ...
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Coal tar, also known as crude tar, is the byproduct generated during the high temperature carbonizing of coking coal for the production of the metallurgical coke in the byproduct coke ovens.
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يرغب أحد موردي المواد من بلجيكا في إنتاج مسحوق الحجر الجيري لملابسه...
الهند غنية بالموارد المعدنية المختلفة وهي سوق مهم لمعالجة المعادن
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