Overall typical composition of a bauxite residue is given in Table 2 and based on the process conditions and region, the bauxite residue composition is tabulated as Table 3 and 4, respectively. Next to the major elements like Fe, Al, Si, Ca, and Na, there are also valuable minor elements such as Ga, V, Zr, and rare earth elements (Evans, 2016).
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Perovskite 1. Introduction Lime is often considered as a panacea in the Bayer process. Its uses are so widespread that there is virtually no unit operation where it does not find an application. Table 1 gives an overview of the main uses of lime in the Bayer process, including low temperature applications (not all applications are given).
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The basis of the Bayer process is an understanding of the characteristics of the sodiumhydroxide—sodiumaluminate solution relationship, namely its ability to keep sodiumaluminate in a dissolved state over a wide range of conditions, especially on the temperature and caustic soda concentrations.
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Following soda and carbon additions, the addition of lime into the sintering process of 20 g CaO to 100 g bauxite residue (80% excess to stoichiometric requirements to form Ca 2 SiO 4) is necessary to investigate the consumption of free and bound silica in desilication products, relying on higher thermodynamic affinity with calcium.
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Diasporic bauxite is the major kind in China, characterized by highaluminum, highsilicon, low ratio of Al2O3 to SiO2 [1], complicated mineral compositions [2] and finely disseminated associations of aluminous minerals and silicate minerals [34]. Presently, to produce aluminum oxide in China is usually not Bayer process but sintering process ...
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Of all Bayer process impurities, few attract more attention than the simplest dicarboxylate. While some oxalate enters the Bayer process with bauxite as oxalic acid adsorbed on various minerals, the majority is created by the oxidation and pyrolysis of bauxite organics under Bayer digestion conditions. The rate of its formation in digestion is ...
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Soda sintering or limesoda sintering process, began from L ouis Le Chatelier's work in 1855 in obtaining aluminum hydroxide (Al(OH) 3 ) from sintering bauxite with soda at around 1000 °C which
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The dominance of Ca in the sintering process is assigned to the excessive addition of lime. Depending upon the refining process adopted by the refinery, Al 2 O 3 ... Wu, Y.: Characterization of red mud derived from a combined Bayer process and bauxite calcination method. J. Hazard. Mater. 146(12), 255261 (2007) Google Scholar ...
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The impact of bauxite slurry pumping on the refining process such as bauxite dewatering, additional evaporation requirements etc. must be taken into account in the design of the alumina plant. ... (= bauxite residue [incl. sand] + lime products) maximum t/tA (dry basis): the bauxite residue ("red mud") leaving the refinery after ...
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The bauxite soda/lime sinter process, used for lowgibbsite highsilica bauxites, is discussed below in Section One of the byproducts of the sinter process is calcium silicate 2CaO·SiO 2, also known as Portland cement. Portland cement is one of the world's largest industrial production products at around 5 billion tonnes a year (an order ...
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Sometimes [when?] lime is added at this stage to precipitate the silica as calcium silicate. The solution is clarified by filtering off the solid impurities, commonly with a rotary sand trap and with the aid of a flocculant such as starch, to remove the fine particles.
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The metallurgical method is a significant technology to extract valuable metals from highsilicon bauxite in industry, which can destroy the complex symbiosis and improve the reactivity by appropriate treatment methods, such as the lime Bayer process (Liu et al., 2018, du Plessis et al., 2021), the sintering process (Yu et al., 2020, Pei et al ...
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In the lime sinter process the additive is a calcium salt (usually calcite — ... Based on the stability field of silica gel formation, a stepwise acid leaching process for bauxite residue is proposed to facilitate downstream processing of the critical metals. Extraction of scandium from bauxite residue by highpressure leaching in sulfuric ...
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The production of alumina (Al2O3) from bauxite via the Bayer process is underpinned by the use of lime in a variety of process reactions. One of the most important is the causticisation of...
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The Bayer process is a chemical process for refining aluminium hydroxide, Al(OH) 3 from bauxite; this aluminium hydroxide is subsequently calcined to produce alumina, Al 2 O 3 . The basis of the ...
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The flotationBayer process has been widely applied in the alumina refineries, but it introduces large amounts of hazardous organic reagents and produces tailings totaling of about 25% of the initial bauxite ores in weight. 25,26 The lime Bayer process has been also employed to process a portion of highsilica bauxite, but it cannot ...
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Additionally, it shows an increase in yields of two points when the lime dosage is low, and between and 3% of the bauxite weight. Based on the mineralogical and chemical composition findings ...
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The Bayer process: How alumina is produced from bauxite. The Bayer process is carried out in four steps. First, after the bauxite is crushed, washed and dried, it is dissolved with caustic soda at high temperatures. Next, the mixture is filtered to remove the impurities, called "red mud," which is properly discarded. The remaining alumina ...
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Based on lime sintering method, a novel process of alumina production from lowgrade bauxite containing sulfur or fly ash is carried out in this paper. The phase of alumina transforms from 12CaO·7Al 2 O 3 (C 12 A 7) to 4CaO·3Al 2 O 3 ·SO 3 (C 4 A 3 S), whose alumina leaching property is better, through decreasing sinter temperature and time ...
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Bauxite residue is a highly salinesodic tailings material formed as a byproduct of the Bayer process for alumina production. In situ remediation of bauxite residue has the potential to provide an effective means for accelerated rehabilitation of residue storage areas. However, previous work has predominantly only used chemical and physical amendments to date, limiting rates of pH ...
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Lime is an essential reagent required in various process steps of the Bayer process, in which bauxite ore is converted into alumina (Whittington et al. 1997), as illustrated in Fig. is used for improving conversion of goethite to hematite and dissolution of boehmite and diaspore during digestion; control of liquor impurities such as silica, oxalate, titanium and phosphorous; minimising ...
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Bayer process, bauxite is mixed with caustic soda, or sodium hydroxide, and heated under pressure. ... The lime slaker is used to prepare lime slurry which is pumped to the digestion unit Area 04 to improve boehmite extraction. Burnt (calcined) lime, which is produced externally, is stored on site in a large ...
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In this process, bauxite is smelted and reduced, which yields pig iron and a calcium aluminate slag. Alumina is further produced from the slag through a hydrometallurgical process. In the present study, different bauxites with different chemical compositions are smelted with lime and reduced by coke.
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The effect of lime on gibbsite bauxite digestion is different from its effect on diaspore bauxite due to its different composition and digestion properties [15, 16]. In one report, gibbsite bauxite was digested by adding 1% lime at 145 °C, achieving a better digestion efficiency of %. However, excessive lime addition will lead to excess ...
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Caption: In a demonstration of the basic chemical reactions used in the new process, electrolysis takes place in neutral water. Dyes show how acid (pink) and base (purple) are produced at the positive and negative electrodes. A variation of this process can be used to convert calcium carbonate (CaCO3) into calcium hydroxide (Ca(OH)2), which can then be used to make Portland cement without ...
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1. Milling The bauxite is washed and crushed, reducing the particle size and increasing the available surface area for the digestion stage. Lime and "spent liquor" (caustic soda returned from the precipitation stage) are added at the mills to make a pumpable slurry. 2. Desilication
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Abstract The recovery of major components of bauxite residue by carbothermic reduction at °C and subsequent slag leaching in a Na3CO3(aq) solution is studied. Iron recovers primarily to pigiron and lime is added to tune the calcium aluminate slags towards the highly leachable mayenite phase. The concentration of aluminum in the leachate correlates well with the occurrence of ...
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The hydrogen reduction of bauxite residue lime pellets at elevated temperatures was carried out to recover iron and alumina from the bauxite residue in a new process route. Prior to the H 2 reduction, oxide pellets were initially prepared via the mixing of an industrial bauxite residue with fine calcite powder followed by calcination and high ...
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Bauxite residue (BR) is generated as a byproduct of the Bayer process. Approximately tons of BR is generated per ton of alumina production but the quantity of bauxite residue depends upon on the quality of the processed bauxite ore and the processing parameter (Primary Aluminium Production).The annual generation of BR in 2019 alone was estimated as 175 million tons (Archambo and Kawatra ...
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During the digestion process of the Bayer method, lithium and gallium in bauxite will enter into the sodium aluminate solution (Tang et al. 2020; Xu et al. 2018 ), which will return to the digestion process for recycling after the precipitation of aluminum hydroxide from the decomposition of crystal species.
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The lime used was industrialgrade lime, and the digestion liquid was prepared by industrial sodium aluminate solution and analyticalgrade sodium ... The review can advance the current technology on the comprehensive utilization of gibbsitic bauxite, especially process discharge reduction approaches and largescale abatement ways for red mud. ...
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The investigational trial explored the unconfined compression strength and stressstrain characteristics of the lime treated soil composites, treated using combinations of 7% lime and %, %, 1% and 2 % bauxite residue. The lime treated soil composites were moulded in to cylindrical specimens of 38 mm diameter and height of 76 mm, cured ...
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A process flow diagram of the Bayer process is shown in Exhibit 3. The primary purpose of a Bayer plant is to process bauxite to provide pure alumina for the production of aluminum. All bauxite refineries share five common process steps: (1) ore preparation; (2) bauxite digestion; (3) clarification; (4) aluminum hydroxide precipi tation; and (5)
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The effect of lime on the predesilication and digestion of gibbsitic bauxite in synthetic sodium aluminate liquor at different temperatures was investigated. The bauxite is comprised of gibbsite, aluminogoethite, hematite, kaolin, quartz, and minor boehmite. Lime increases the desilication efficiency of the bauxite during the predesilication process by promoting the conversion of sodalite ...
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